CobaltMaghrebV1, France, Analysis, bibRecord, 000057

(2.2.2-Cryptand)potassium bis(cyanato-κN)(5,10,15,20-tetraphenylporphyrinato-κ4N)cobaltate(III) chlorobenzene hemisolvate

Identifieur interne : 000057 ( France/Analysis ); précédent : 000056; suivant : 000058

(2.2.2-Cryptand)potassium bis(cyanato-κN)(5,10,15,20-tetraphenylporphyrinato-κ4N)cobaltate(III) chlorobenzene hemisolvate

Auteurs : Bader Belhaj Ali [Tunisie] ; Mohamed Salah Belkhiria [Tunisie] ; Jean-Claude Daran [France] ; Habib Nasri [Tunisie]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2012.

RBID : PMC:3470147

Abstract

In the title compound, [K(C₁₈H₃₆N₂O₆)][Co(NCO)₂(C₄₄H₂₈N₄)]·0.5C₆H₅Cl or [K(2,2,2-crypt)⁺][Co^III(NCO)₂(TPP)⁻]·0.5C₆H₅Cl, the Co^III ion is octahedrally coordinated by two axial N-bonded NCO⁻ anions and four pyrrole N atoms of the porphyrin. There is a major ruffling distortion of the porphyrin: the dihedral angles between trans pyrrole rings are 34.32 (14) and 34.72 (14)°. The potassium ion is coordinated by the six O atoms and two N atoms of the cryptand-222 molecule and a weak K—O [3.407 (3) Å] bond to one of the cyanate O atoms also occurs. The packing also features weak C—H⋯O and C—H⋯π interactions. The contribution to the scattering of the disordered chlorobenzene solvent molecules was removed with the SQUEEZE function in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155].

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470147

DOI: 10.1107/S1600536812038317
PubMed: 23125591
PubMed Central: 3470147

Affiliations:

France, Tunisie

Links to Exploration step

PMC:3470147

Le document en format XML

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<front><div type="abstract" xml:lang="en"><p>In the title compound, [K(C<sub>18</sub>
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H<sub>28</sub>
N<sub>4</sub>
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H<sub>5</sub>
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H<sub>5</sub>
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). <italic>Acta Cryst.</italic>
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Serveur d'exploration sur le cobalt au Maghreb

(2.2.2-Cryptand)potassium bis(cyanato-κN)(5,10,15,20-tetraphenylporphyrinato-κ4N)cobaltate(III) chlorobenzene hemisolvate

(2.2.2-Cryptand)potassium bis(cyanato-κN)(5,10,15,20-tetraphenylporphyrinato-κ4N)cobaltate(III) chlorobenzene hemisolvate

Source :

Abstract

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Links to Exploration step

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Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

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	Serveur d'exploration sur le cobalt au Maghreb
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Serveur d'exploration sur le cobalt au Maghreb

(2.2.2-Cryptand)potassium bis­(cyanato-κN)(5,10,15,20-tetra­phenyl­por­phy­rin­ato-κ4N)cobaltate(III) chloro­benzene hemisolvate

(2.2.2-Cryptand)potassium bis­(cyanato-κN)(5,10,15,20-tetra­phenyl­por­phy­rin­ato-κ4N)cobaltate(III) chloro­benzene hemisolvate

Source :

Abstract

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Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

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Pour générer des pages wiki

(2.2.2-Cryptand)potassium bis(cyanato-κN)(5,10,15,20-tetraphenylporphyrinato-κ4N)cobaltate(III) chlorobenzene hemisolvate

(2.2.2-Cryptand)potassium bis(cyanato-κN)(5,10,15,20-tetraphenylporphyrinato-κ4N)cobaltate(III) chlorobenzene hemisolvate